Gem-quality sapphires containing ‘exotic’ elements such as Sn, Nb, Zr, Ta, W, are of special interest in gemmological research, as the concentration of these so-called high-field- strength-elements (HFSE) often correlate with detectable traces of naturally incorporated beryllium (Whatanakul et al. 2004, Par

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Titanium diffusion treatment is known since decades: it can lead to a surface-related blue colour in corundum. Basically, this treatment is a heating process requiring high temperatures in combination with titanium (oxide) as an additive. During the treatment, titanium atoms penetrate into a superficial layer o